Recent Applications of Solid-Supported Ammonium Fluorides in Organic Synthesis

Daniela Lanari; Oriana Piermatti; Chiara Morozzi; Stefano Santoro; Luigi Vaccaro

doi:10.1055/s-0036-1588088

Synthesis, Table of Contents

Synthesis 2017; 49(05): 973-980
DOI: 10.1055/s-0036-1588088

short review

Recent Applications of Solid-Supported Ammonium Fluorides in Organic Synthesis

Daniela Lanari

^aDipartimento di Scienze Farmaceutiche, Università di Perugia, Via del Liceo 1, 06123 Perugia, Italy

,

Oriana Piermatti

^bLaboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy Email: luigi.vaccaro@unipg.it

,

Chiara Morozzi

^aDipartimento di Scienze Farmaceutiche, Università di Perugia, Via del Liceo 1, 06123 Perugia, Italy

,

Stefano Santoro

^bLaboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy Email: luigi.vaccaro@unipg.it

,

Luigi Vaccaro*

^bLaboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy Email: luigi.vaccaro@unipg.it

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Abstract

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Abstract

This review summarizes recent contributions on the use of fluoride catalysts immobilized on polymer supports. Besides the commercially available Amberlyst fluoride, TBAF on silica gel, and TBAF on alumina, that have proved widely useful for several interesting and valuable synthetic C–N, C–O, and C–C bond transformations, novel catalysts based on the DABCO moiety have allowed access to very useful, new transformations.

1 Introduction

2 Polystyryl-DABCOF₂

3 Polystyryl-DABCOF

4 Amberlyst Fluoride (Amb-F)

5 TBAF on Alumina or on Silica Gel

6 Conclusion

Key words

heterogeneous catalysis - green chemistry - fluoride catalysis - polymer-supported catalysts

Full Text

References

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