Nano-Magnetic Sulfonic Acid Catalyzed Facile Synthesis of Diverse Amide Derivatives

Abstract

The excellent surface catalytic potential of Fe₃O₄–OSO₃H is utilized in the synthesis of symmetrically and unsymmetrically substituted urea derivatives via transamidation reactions. The scope of the surface catalysis is further extended in transamidation reactions of cyclic and acyclic amide derivatives, and in the amidation of fatty acids. In both transamidation and amidation reactions, the catalyst is reusable up to five times without significant loss in its activity.

Key words

magnetic sulfonic acid - green synthesis - transamidation - fatty acid amidation - chemoselectivity

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