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Synthesis 2017; 49(07): 1555-1560
DOI: 10.1055/s-0036-1588667
DOI: 10.1055/s-0036-1588667
paper
A Regioselective and Convergent Paired Electrochemical Synthesis of N,N′-Diphenyl-3-sulfonyl-[1,1′-biphenyl]-4,4′-diamines
Weitere Informationen
Publikationsverlauf
Received: 07. September 2016
Accepted after revision: 11. November 2016
Publikationsdatum:
13. Dezember 2016 (online)
![](https://www.thieme-connect.de/media/synthesis/201707/lookinside/thumbnails/ss-2016-z0617-op_10-1055_s-0036-1588667-1.jpg)
Abstract
A regioselective synthesis of N,N′-diphenyl-3-sulfonyl-[1,1′-biphenyl]-4,4′-diamine derivatives is carried out by anodic oxidation of N,N′-diphenylbenzidine in the presence of sulfinic acids as nucleophiles via a convergent paired electrochemical process. The sulfonylated aromatic amine products are obtained under mild reaction conditions with high yields, high current efficiency and atom economy.
Key words
regioselective synthesis - electrosynthesis - Michael acceptors - cyclic voltammetry - convergent paired synthesis - N,N′-diphenylbenzidineSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588667.
- Supporting Information
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