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Synthesis 2017; 49(21): 4769-4774
DOI: 10.1055/s-0036-1588848
DOI: 10.1055/s-0036-1588848
special topic
Palladium-Catalyzed Double Borylation of Diaryl Sulfoxides with Diboron
This work was supported by JSPS KAKENHI Grant Numbers JP16H01019, JP16H01149, JP16H04109, and JP16H06887 as well as by ACT-C, JST. H.Y. thanks Japan Association for Chemical Innovation, Tokuyama Science Foundation, and The Naito Foundation for financial support.Further Information
Publication History
Received: 01 April 2017
Accepted after revision: 04 May 2017
Publication Date:
29 May 2017 (online)
![](https://www.thieme-connect.de/media/synthesis/201721/lookinside/thumbnails/ss-2017-c0217-st_10-1055_s-0036-1588848-1.jpg)
Published as part of the Special Topic Modern Strategies for Borylation in Synthesis
Abstract
Borylation of the C–S bond of diaryl sulfoxides with bis(pinacolato)diboron (B2pin2) is accomplished by means of a phosphine-ligated palladium catalyst and LiN(SiMe3)2 as a base. Both of the aryl rings of the diaryl sulfoxides are converted into borylated products.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588848.
- Supporting Information
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For reviews, see:
For borylation of aryl carbamates and esters, see:
For borylation of aryl ethers, see:
For borylation of N-aryl amides, see:
For borylation of ammonium salts, see:
Reviews: