Peroxide-Free Co(OAc)2-Catalyzed Radical Addition of sp3 C–H Bonds to Alkynes

Min Zhang; Yun Zhao; Wanzhi Chen

doi:10.1055/s-0036-1588909

Synthesis, Inhaltsverzeichnis

Synthesis 2017; 49(06): 1342-1348
DOI: 10.1055/s-0036-1588909

paper

Peroxide-Free Co(OAc)₂-Catalyzed Radical Addition of sp³ C–H Bonds to Alkynes

Min Zhang

Department of Chemistry, Zhejiang University, Hangzhou 310013, P. R. of China eMail: chenwzz@zju.edu.cn

,

Yun Zhao

Department of Chemistry, Zhejiang University, Hangzhou 310013, P. R. of China eMail: chenwzz@zju.edu.cn

,

Wanzhi Chen*

Department of Chemistry, Zhejiang University, Hangzhou 310013, P. R. of China eMail: chenwzz@zju.edu.cn

› Institutsangaben

Abstract

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Abstract

Cobalt-catalyzed radical addition of C–H bonds adjacent to an oxygen atom towards alkynes is described. The reaction proceeded at 60 °C without using additional radical initiators, and leads to 2-vinyl ether derivatives in good yields.

Key words

cobalt catalysis - radical addition - alkyne - tetrahydrofuran

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Referenzen

References

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