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Synthesis 2017; 49(06): 1168-1181
DOI: 10.1055/s-0036-1588922
DOI: 10.1055/s-0036-1588922
short review
Metal Acetylides in Cycloaddition Reactions
Further Information
Publication History
Received: 27 September 2016
Accepted after revision: 14 November 2016
Publication Date:
08 December 2016 (online)
Abstract
This review highlights recent advances in the synthesis of (hetero)aromatic systems via cycloaddition reactions of alkynylmetals with dienes and dipoles. This methodology is advantageous when accessing complex molecules because it offers a short, atom-economic, and regioselective route to quickly access scaffolds of broad interest to the chemical sciences.
1 Introduction
2 Synthesis and Applications of Metal Acetylides
3 Use of Metal Acetylides in Cycloaddition Reactions
3.1 The CuSAC Reaction
3.2 The Kinugasa Coupling with Copper Acetylides
3.3 Reactions of Pyrones and Aluminum Acetylides
3.4 Direct Cycloadditions of Boron Acetylides
4 Conclusion
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