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Synlett 2017; 28(15): 1873-1884
DOI: 10.1055/s-0036-1589008
DOI: 10.1055/s-0036-1589008
account
Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents
Further Information
Publication History
Received: 25 February 2017
Accepted after revision: 27 March 2017
Publication Date:
04 May 2017 (online)
Abstract
The silicon-based cross-coupling reaction has attracted much attention over recent decades because there are many advantages in using organosilicon compounds. However, the use of reagents with a triorganosilyl group as a key function remains to be established. This account summarizes our recent progress in cross-coupling chemistry with such silyl reagents.
1 Introduction
2 Preparation of HOMSi Reagents from Aryl Bromides and Disilanes
3 HOMSi Reagents from Heteroaromatics and Hydrosilanes
4 Cross-Coupling Polymerization with HOMSi Reagents
5 Cross-Coupling with Aryl(triethyl)silanes
6 Amination of Aryl Halides with N-TMS-Amines
7 Conclusion and Perspective
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For recent reviews, see:
For recent examples, see:
For recent examples, see:
For recent reviews, see:
For selected examples of intermolecular catalytic dehydrogenative silylation of arenes without any directing group, see:
For recent reviews on the cross-coupling polymerization, see:
For reactions via single-electron transfer from silicates, see:
For reviews, see:
For selected examples, see:
For pioneering work on the Pd-catalyzed C–N cross-coupling polymerization, see: