Pd/Indanone-Based Ligands: An Efficient Catalyst System for Ullmann­-Type, Suzuki–Miyaura, and Mizoroki–Heck Cross-Coupling Reactions with Aryl Tosylates and Aryl Halides

Mohammed Waheed; Naseem Ahmed

doi:10.1055/s-0036-1589058

Synthesis, Table of Contents

Synthesis 2017; 49(18): 4372-4382
DOI: 10.1055/s-0036-1589058

paper

Pd/Indanone-Based Ligands: An Efficient Catalyst System for Ullmann-Type, Suzuki–Miyaura, and Mizoroki–Heck Cross-Coupling Reactions with Aryl Tosylates and Aryl Halides

Mohammed Waheed *

Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India Email: nasemfcy@iitr.ac.in

,

Naseem Ahmed*

Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India Email: nasemfcy@iitr.ac.in

› Author Affiliations

Abstract

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Abstract

2-Hydroxyindan-1-ones have been efficiently synthesized and successfully applied as ligands in Pd-catalyzed Ullmann type, Suzuki–Miyaura, and Mizoroki–Heck cross-coupling reactions with aryl tosylates and aryl halides. The ligands are air- and moisture-stable and have shown high catalytic activity with Pd(OAc)₂ in these cross-coupling reactions. The system tolerates a variety of functional groups in the product and can be re-used at least three times with maximum efficiency.

Key words

palladium acetate - Ullmann coupling - Suzuki coupling - Heck coupling - catalyst recycling

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References

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Supporting Information

Pd/Indanone-Based Ligands: An Efficient Catalyst System for Ullmann­-Type, Suzuki–Miyaura, and Mizoroki–Heck Cross-Coupling Reactions with Aryl Tosylates and Aryl Halides

Pd/Indanone-Based Ligands: An Efficient Catalyst System for Ullmann-Type, Suzuki–Miyaura, and Mizoroki–Heck Cross-Coupling Reactions with Aryl Tosylates and Aryl Halides