Recent Advances in the Asymmetric Nozaki–Hiyama–Kishi Reaction

Abstract

This review will survey recent developments in the area of the catalytic asymmetric Nozaki–Hiyama–Kishi reaction. The content will be classified according to reaction type as follows: asymmetric allylation, asymmetric propargylation, asymmetric alkynylation, asymmetric vinylation, and asymmetric alkylation.

1 Introduction

2 Asymmetric Allylation

3 Asymmetric Propargylation and Asymmetric Homoallenylation

4 Asymmetric Alkynylation

5 Asymmetric Vinylation and Arylation

6 Asymmetric Alkylation

7 Intramolecular Nozaki–Hiyama–Kishi Reaction

8 Conclusion and Perspectives

Key words

asymmetric catalysis - chromium - NHK reaction - aldehydes - C–C bond formation

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