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Synthesis 2017; 49(07): 1419-1443
DOI: 10.1055/s-0036-1589478
DOI: 10.1055/s-0036-1589478
review
Recent Developments in Cobalt Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation via C–H Bond Functionalization
Weitere Informationen
Publikationsverlauf
Received: 19. September 2016
Accepted after revision: 19. Oktober 2016
Publikationsdatum:
06. Februar 2017 (online)
Abstract
Cobalt catalysts have evolved to be seen as versatile eco-compatible and economical catalysts in organic synthesis in recent years. Cobalt-catalyzed reactions are undoubtedly a classic in synthetic chemistry for the formation of carbon–carbon and carbon–heteroatom bonds. Another important aspect in this field is catalyst variants, such as low-valent and high-valent cobalt catalysts. This review summarizes the recent progress and synthetic utility of low-valent and high-valent cobalt catalysts towards C–H functionalization processes achieving C–C, C–O, C–N and C–B bond formation. Mechanistic insight is also discussed, with the goal of serving as a stepping stone for further development in this field. In addition, Csp3–H bond functionalization reactions provide many opportunities for novel synthesis approaches.
1 Introduction
2 Carbon–Carbon Bond Formation
2.1 Csp2–Csp3 Bond Formation
2.2 Csp2–Csp2 Bond Formation
3 Carbon–Nitrogen Bond Formation
4 Csp3–H Bond Functionalization
5 Carbon–Oxygen Bond Formation
6 Carbon–Boron Bond Formation
7 Conclusion
-
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For references on Co(I)-catalysis, see:
For cobalt-catalyzed hydrosilylation, see: