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Synthesis 2018; 50(15): 2999-3005
DOI: 10.1055/s-0036-1591575
DOI: 10.1055/s-0036-1591575
special topic
Visible-Light-Driven Oxidation of N-Alkylamides to Imides Using Oxone/H2O and Catalytic KBr
Authors
We thank the National Natural Science Foundation of China (Grant No. 21372153) for financial support.
Weitere Informationen
Publikationsverlauf
Received: 26. Februar 2018
Accepted after revision: 03. April 2018
Publikationsdatum:
16. Mai 2018 (online)
Published as part of the Special Topic Modern Radical Methods and their Strategic Applications in Synthesis
Abstract
Imides are prepared conveniently by visible-light-driven oxidations of various N-alkylamides under mild conditions. The majority of the reactions proceed efficiently by using Oxone as the oxidant in the presence of a catalytic amount of KBr in H2O/CH2Cl2 under irradiation by an 8 W white LED at room temperature. Experimental studies suggest that an imine, obtained from the substrate amide via a radical process, is the key intermediate.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1591575.
- Supporting Information (PDF)
-
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