Continuous Flow Conversion of Glycerol into Chemicals: An Overview

Christophe Len; Frederic Delbecq; Cristobal Cara Corpas; Encarnacion Ruiz Ramos

doi:10.1055/s-0036-1591857

Synthesis, Table of Contents

Synthesis 2018; 50(04): 723-741
DOI: 10.1055/s-0036-1591857

short review

Continuous Flow Conversion of Glycerol into Chemicals: An Overview

Christophe Len *

^aSorbonne Universités, Université de Technologie de Compiègne, Centre de Recherche Royallieu, CS 60 319, 60203 Compiègne Cedex, France Email: christophe.len@utc.fr

^bPSL Research University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05, France

,

Frederic Delbecq

^cEcole Supérieure de Chimie Organique et Minérale, 1 allée du Réseau Jean-Marie Buckmaster, 60200 Compiègne, France

,

Cristobal Cara Corpas

^dUniversidad de Jaen, Department of Chemical, Environmental and Materials Engineering, Campus Las Lagunillas, 23071 Jaén, Spain

^eUniversidad de Jaen, Center for Advances Studies in Energy and Environment (CEAEMA), 23071 Jaén, Spain

,

Encarnacion Ruiz Ramos

^dUniversidad de Jaen, Department of Chemical, Environmental and Materials Engineering, Campus Las Lagunillas, 23071 Jaén, Spain

^eUniversidad de Jaen, Center for Advances Studies in Energy and Environment (CEAEMA), 23071 Jaén, Spain

› Author Affiliations

Abstract

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Abstract

This report highlights the recent advances for glycerol valorization to valuable products in liquid phase continuous flow systems using different types of catalysts and processes. The main biobased chemicals obtained from glycerol, such as acrolein, lactic acid, dihydroxyacetone, propanediols, glycerol carbonate, solketal, acetin, alkyl ethers, and oligomers, will be presented.

1 Introduction

2 Continuous Dehydration

2.1 Without Added Catalyst

2.2 With Acid Catalyst

3 Continuous Oxidation

4 Continuous Hydrogenolysis

5 Continuous Carbonatation

6 Continuous Ketalization

7 Continuous Esterification

8 Continuous Etherification

9 Continuous Oligomerization

10 Outlook

11 Conclusion

Key words

glycerol - continuous flow - green chemistry - catalysis

Full Text

References

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