Regioselective Approach to 5-Carboxy-1,2,3-triazoles Based on Palladium-Catalyzed Carbonylation

Yury N. Kotovshchikov; Gennadij V. Latyshev; Irina P. Beletskaya; Nikolay V. Lukashev

doi:10.1055/s-0036-1591896

Synthesis, Table of Contents

Synthesis 2018; 50(09): 1926-1934
DOI: 10.1055/s-0036-1591896

paper

Regioselective Approach to 5-Carboxy-1,2,3-triazoles Based on Palladium-Catalyzed Carbonylation

Yury N. Kotovshchikov

Chemistry Department, M. V. Lomonosov Moscow State University, 1/3 Leninskiye Gory, Moscow 119991, Russian Federation Email: latyshev@org.chem.msu.ru

,

Gennadij V. Latyshev*

Chemistry Department, M. V. Lomonosov Moscow State University, 1/3 Leninskiye Gory, Moscow 119991, Russian Federation Email: latyshev@org.chem.msu.ru

,

Irina P. Beletskaya

Chemistry Department, M. V. Lomonosov Moscow State University, 1/3 Leninskiye Gory, Moscow 119991, Russian Federation Email: latyshev@org.chem.msu.ru

,

Nikolay V. Lukashev

Chemistry Department, M. V. Lomonosov Moscow State University, 1/3 Leninskiye Gory, Moscow 119991, Russian Federation Email: latyshev@org.chem.msu.ru

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Abstract

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Abstract

A regioselective two-step approach to 5-carboxy-1,2,3-triazoles based on palladium-catalyzed carbonylation has been developed. The protocol utilizes readily available 5-iodotriazoles as starting materials. The obtained products were used in the syntheses of fused heterocycles as well as derivatization of the steroidal hormone cortexolone.

Key words

1,2,3-triazole - carbonylation - catalysis - palladium - copper

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References

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