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Synthesis 2018; 50(24): 4846-4854
DOI: 10.1055/s-0037-1609934
DOI: 10.1055/s-0037-1609934
paper
Microwave-Assisted Syntheses of Thiophene-Based Ionic Liquids: Structural Design and Optimization
Further Information
Publication History
Received: 29 June 2018
Accepted after revision: 29 July 2018
Publication Date:
21 August 2018 (online)
Abstract
This manuscript explores microwave-assisted reactions for the synthesis of new ionic materials involving the S-alkylation of thiophene. All isolatable products have been fully characterized by NMR and all product have been quantified through UV-vis spectroscopy. By means of a design technique, the experimental protocol (25 min, 200 W, 50 °C) has been optimized, which led us to better yields (96 %). In the absence of MW activation, the conventional thermal reaction at room temperature took longer (24 – 48 h) to obtain similar results.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055 /s-0037 – 1609934.
- Supporting Information
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