Recent Advances in the Applications of Triethylsilane in Organic Synthesis

Veronika Ručilová; Miroslav Soural

doi:10.1055/s-0037-1610107

Synthesis, Table of Contents

Synthesis 2018; 50(19): 3809-3824
DOI: 10.1055/s-0037-1610107

short review

Recent Advances in the Applications of Triethylsilane in Organic Synthesis

Veronika Ručilová

^aDepartment of Organic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic

,

Miroslav Soural*

^bInstitute of Molecular and Translation Medicine, Faculty of Medicine and Dentistry, Palacký University, Hněvotínská 5, 779 00, Olomouc, Czech Republic Email: miroslav.soural@upol.cz

› Author Affiliations

Abstract

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Abstract

The synthesis of pharmacologically relevant scaffolds is an important goal in modern organic chemistry. For this reason, the use of methodologies involving operationally simple procedures and easily handled reagents to chemoselectively and stereoselectively convert different functionalities has gained considerable attention. In this review, we summarize the latest trends in reductive reactions using triethylsilane as the key reagent that provide synthetically interesting intermediates, coupling products and structures with control of the 3D architecture.

1 Introduction

2 Scenario A: Reduction of C–C Multiple Bonds

3 Scenario B: Reduction of Functional Groups

4 Scenario C: Reductive Coupling

5 Scenario D: Reductive Cyclization

6 Conclusion

Key words

triethylsilane - reduction - reductive coupling - reductive cyclization - heterocycles

Full Text

References

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