Synthesis, Inhaltsverzeichnis

Synthesis 2018; 50(17): 3359-3378
DOI: 10.1055/s-0037-1610222

special topic

© Georg Thieme Verlag Stuttgart · New York

Merging Transition-Metal Catalysis with Photoredox Catalysis: An Environmentally Friendly Strategy for C–H Functionalization

Wen-Jun Zhou*

^aCollege of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641112, P. R. of China eMail: chemzhwj@126.com

^bKey Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. of China eMail: dgyu@scu.edu.cn

,

Yi-Han Zhang

^bKey Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. of China eMail: dgyu@scu.edu.cn

,

Yong-Yuan Gui

^bKey Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. of China eMail: dgyu@scu.edu.cn

,

Liang Sun

^bKey Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. of China eMail: dgyu@scu.edu.cn

,

Da-Gang Yu *

^bKey Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. of China eMail: dgyu@scu.edu.cn

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Published as part of the Special Topic Photoredox Methods and their Strategic Applications in Synthesis

^‡ These authors contributed equally.

Abstract

Transition-metal-catalyzed C–H functionalization is already a useful tool in organic synthesis, whilst the rapid development of photoredox catalysis provides new pathways for C–H functionalization with high selectivity and efficiency under mild reaction conditions. In this review, recent advances in C–H functionalization through merging transition-metal catalysis with photoredox catalysis are discussed.

1 Introduction

2 Merging Nickel Catalysis with Photoredox Catalysis

3 Merging Palladium Catalysis with Photoredox Catalysis

4 Merging Cobalt Catalysis with Photoredox Catalysis

5 Merging Photoredox Catalysis with Other Transition-Metal Catalysis

6 Conclusions

Key words

Key words

transition-metal catalysis - photoredox catalysis - C–H functionalization - selectivity - mild reaction conditions

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