Metal-Free Synthesis of Biaryl- and Teraryl-Cored Diarylmethanes by Ring Transformation of 2H-Pyran-2-ones

Fateh V. Singh; Priyanka B. Kole

doi:10.1055/s-0037-1610332

Synthesis, Table of Contents

Synthesis 2019; 51(06): 1435-1444
DOI: 10.1055/s-0037-1610332

paper

Metal-Free Synthesis of Biaryl- and Teraryl-Cored Diarylmethanes by Ring Transformation of 2H-Pyran-2-ones

Fateh V. Singh *

Chemistry Division, School of Advanced Science, VIT University, Chennai Campus, Chennai 600127, Tamil Nadu, India Email: fatehveer.singh@vit.ac.in

,

Priyanka B. Kole

› Author Affiliations

Abstract

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Abstract

An efficient metal-free approach for the synthesis of functionalized biaryl-cored diarylmethanes is described by the ring transformation of 2H-pyran-2-ones using 4-phenylbutan-2-one as carbanion source. Moreover, 2H-pyran-2-ones were reacted with 1,3-diphenylacetone in the presence of base to achieve functionalized teraryl-cored diarylmethanes. All the ring transformation reactions were performed under mild reaction conditions to afford the biaryl- and teraryl-cored reaction products in high yields.

Key words

biaryl-cored diarylmethanes - teraryl-cored diarylmethanes - 2H-pyran-2-ones - carbanion - ring transformation reactions - 4-phenylbutan-2-one - 1,3-diphenylacetone

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References

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