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CC BY-ND-NC 4.0 · Synthesis 2019; 51(01): 161-177
DOI: 10.1055/s-0037-1610393
DOI: 10.1055/s-0037-1610393
short review
Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
Further Information
Publication History
Received: 30 October 2018
Accepted: 31 October 2018
Publication Date:
27 November 2018 (online)
This paper is dedicated to Dr. Holger Butenschön (Leibniz Universität Hannover) on the occasion of his 65th birthday.
Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue
Abstract
Tris(acetylacetonato) iron(III) [Fe(acac)3] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac)3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac)3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses.
1 Introduction
2 Hydrogen Atom Transfer (HAT)
3 Oxidations and Radical Transformations
4 Synthesis and Use of Alkynes and Allenes
5 Cross-Couplings and Cycloisomerizations
6 Borylations
7 Miscellaneous Reactions
8 Conclusions
-
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For further reviews on HAT-based olefin functionalization, see: