Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

Naohiko Yoshikai

doi:10.1055/s-0037-1610397

Synthesis, Table of Contents

CC BY-ND-NC 4.0 · Synthesis 2019; 51(01): 135-145
DOI: 10.1055/s-0037-1610397

short review

Copyright with the author

Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

Naohiko Yoshikai *

Abstract

All articles of this category

Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue

Abstract

This Short Review describes recent developments in cobalt-catalyzed enantioselective C–C bond-forming reactions. The article focuses on reactions that most likely involve chiral organocobalt species as crucial catalytic intermediates and their mechanistic aspects.

1 Introduction

2 Hydrovinylation

3 C–H Functionalization

4 Cycloaddition and Cyclization

5 Addition of Carbon Nucleophiles

6 Cross-Coupling

7 Conclusion

Key words

cobalt - asymmetric catalysis - C–C bond formation - hydrovinylation - C–H functionalization - cyclization, cross-coupling

Full Text

References

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