Recent Developments in Palladium-Catalysed Non-Directed C–H Bond Activation in Arenes

Sindhu Kancherla; Kåre B. Jørgensen; M. Ángeles Fernández-Ibáñez

doi:10.1055/s-0037-1610852

Synthesis, Inhaltsverzeichnis

Synthesis 2019; 51(03): 643-663
DOI: 10.1055/s-0037-1610852

short review

Recent Developments in Palladium-Catalysed Non-Directed C–H Bond Activation in Arenes

Sindhu Kancherla

^aDepartment of Chemistry, Bioscience and Environmental Technology, Faculty of Science and Technology, University of Stavanger, P.O. Box 8600 Forus, N-4036 Stavanger, Norway eMail: kare.b.jorgensen@uis.no

,

Kåre B. Jørgensen *

^aDepartment of Chemistry, Bioscience and Environmental Technology, Faculty of Science and Technology, University of Stavanger, P.O. Box 8600 Forus, N-4036 Stavanger, Norway eMail: kare.b.jorgensen@uis.no

,

M. Ángeles Fernández-Ibáñez *

^bVan’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands eMail: m.a.fernandezibanez@uva.nl

› Institutsangaben

Abstract

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Abstract

Over the past decades, organic chemists have focussed on developing new approaches to directed C–H functionalisations, where the site selectivity is steered by the presence of a directing group (DG). Nonetheless, in recent years, more and more non-directed strategies are being developed to circumvent the requisite directing group, making C–H functionalisations more generic. This short review focuses on the latest developments in palladium-catalysed non-directed C–H functionalisations of aromatic compounds.

1 Introduction

2 C–C Bond Formation

2.1 C–H Arylation

2.2 C–H Alkylation

2.3 C–H Alkenylation

2.4 C–H Carbonylation

3 C–Heteroatom Bond Formation

3.1 C–O Bond Formation

3.2 C–N Bond Formation

3.3 C–S Bond Formation

4 Conclusion

Key words

C–H bond activation - palladium - non-directed - arenes - catalysis

Volltext

Referenzen

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