Synthesis, Inhaltsverzeichnis Synthesis 2019; 51(03): 739-746DOI: 10.1055/s-0037-1611058 paper © Georg Thieme Verlag Stuttgart · New York Selective Conversion of CO2 and Switchable Alcohols into Linear or Cyclic Carbonates via Versatile Zinc Catalysis Qing-Wen Song * State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, South Taoyuan Road 27, Taiyuan, 030001, P. R. China eMail: songqingwen@sxicc.ac.cn eMail: pingliu@sxicc.ac.cn , Qing-Ning Zhao , Jing-Yuan Li , Kan Zhang , Ping Liu* › Institutsangaben Artikel empfehlen Abstract Artikel einzeln kaufen Alle Artikel dieser Rubrik Abstract It is promising and challenging to achieve the effective construction of carbonates using CO2 and a non-noble metal catalyst. Herein, selective catalytic conversion of CO2 and switchable alcohol candidates to produce linear or cyclic carbonates and α-hydroxy ketones via effective zinc catalyst was developed. A series of primary alcohols and cyclohexanol, 1,2-diols, and water can serve as nucleophiles to give alkyl or aryl 2-substituted-3-oxobutan-2-yl carbonates, substituted 1,3-dioxolan-2-ones, 3-substituted 3-hydroxybutan-2-ones, respectively with excellent selectivity and high yields. Key words Key wordscarbon dioxide utilization - carbonates - zinc catalysis - multicomponent reaction - synthetic methods Volltext Referenzen References 1a Yang Z.-Z, He L.-N, Gao J, Liu A.-H, Yu B. Energy Environ. Sci. 2012; 5: 6602 1b Aresta M, Dibenedetto A, Angelini A. Chem. Rev. 2014; 114: 1709 1c Liu Q, Wu L, Jackstell R, Beller M. Nat. Commun. 2015; 6: 5933 1d He M, Sun Y, Han B. Angew. Chem. Int. Ed. 2013; 52: 9620 1e Wang WH, Himeda Y, Muckerman JT, Manbeck GF, Fujita E. Chem. Rev. 2015; 115: 12936 1f Song Q.-W, Zhou Z.-H, He L.-N. Green Chem. 2017; 19: 3707 1g Zhang Q, Yuan H.-Y, Fukaya N, Yasuda H, Choi J.-C. Green Chem. 2017; 19: 5614 For selected reviews, see: 2a Lu X.-B, Darensbourg DJ. 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