Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

Lena Blank; Maurizio Fagnoni; Stefano Protti; Magnus Rueping

doi:10.1055/s-0037-1611648

Synthesis, Table of Contents

CC BY-ND-NC 4.0 · Synthesis 2019; 51(05): 1243-1252
DOI: 10.1055/s-0037-1611648

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Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

Lena Blank

^aInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany Email: magnus.rueping@rwth-aachen.de

,

Maurizio Fagnoni

^bPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli, 12, 27100 Pavia, Italy

,

Stefano Protti

^bPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli, 12, 27100 Pavia, Italy

,

Magnus Rueping *

^aInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany Email: magnus.rueping@rwth-aachen.de

› Author Affiliations

Abstract

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Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue

Abstract

A green, efficient, photoinduced synthesis of arylboronic esters and aryl sulfides has been developed. Bench stable arylazo sulfones were used as radical precursors for a photocatalyst- and additive-free carbon–heteroatom bond formation under visible light. The protocols are applicable to a wide range of substrates, providing products in good yields.

Key words

arylazo sulfones - aryl radicals - arylboronic esters - aryl sulfides

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References

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