Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue

Abstract

A green, efficient, photoinduced synthesis of arylboronic esters and aryl sulfides has been developed. Bench stable arylazo sulfones were used as radical precursors for a photocatalyst- and additive-free carbon–heteroatom bond formation under visible light. The protocols are applicable to a wide range of substrates, providing products in good yields.

Key words

arylazo sulfones - aryl radicals - arylboronic esters - aryl sulfides

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