Pyrroles as Dienes in (4+3) Cycloadditions

Fan Hu; Jerome P. L. Ng; Pauline Chiu

doi:10.1055/s-0037-1611660

Synthesis, Inhaltsverzeichnis

CC BY-ND-NC 4.0 · Synthesis 2019; 51(05): 1073-1086
DOI: 10.1055/s-0037-1611660

short review

Copyright with the author

Pyrroles as Dienes in (4+3) Cycloadditions

Fan Hu

,

Jerome P. L. Ng

,

Pauline Chiu *

State Key Laboratory of Synthetic Chemistry, Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. of China eMail: pchiu@hku.hk

› Institutsangaben

Abstract

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Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue

Abstract

This short review summarizes the examples to date of successful (4+3) cycloadditions, including formal (4+3) cycloadditions, where pyrrole derivatives reacted as the diene component, to provide aza-bridged bicyclic and polycyclic adducts.

1 Introduction

2 Unsubstituted Pyrroles as Dienes in (4+3) Cycloadditions

3 C-Substituted Pyrroles as Dienes in (4+3) Cycloadditions

4 Intramolecular Pyrrole (4+3) Cycloadditions

5 Conclusions

Key words

(4+3) cycloadditions - pyrroles - oxyallylic cations - tropanes - alkaloids - aza-bridge - cyclopropanation - Cope rearrangement

Volltext

Referenzen

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