Catalytic Hydrogenations with Cationic Heteroleptic Copper(I)/N-Heterocyclic Carbene Complexes

Niklas O. Thiel; Lea T. Brechmann; Johannes F. Teichert

doi:10.1055/s-0037-1612302

Synlett, Table of Contents

Synlett 2019; 30(07): 783-786
DOI: 10.1055/s-0037-1612302

letter

Catalytic Hydrogenations with Cationic Heteroleptic Copper(I)/N-Heterocyclic Carbene Complexes

Niklas O. Thiel

,

Lea T. Brechmann

,

Johannes F. Teichert *

Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 115, 10623 Berlin, Germany Email: johannes.teichert@chem.tu-berlin.de

› Author Affiliations

Abstract

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Published as part of the Special Section 10th EuCheMS Organic Division Young Investigator Workshop

Abstract

A new heteroleptic cationic copper(I) complex bearing two N-heterocyclic carbene (NHC) ligands has been prepared. In situ, a Cu–O bond can be generated which enables the complex to catalytically activate H₂. The resulting complex shows activity in catalytic chemo- and stereoselective alkyne semihydrogenations as well as conjugate reductions of enones.

Key words

copper - NHC ligands - hydrogenation - homogeneous catalysis - alkynes - enones

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References

References and Notes
1 Present address: Stratingh Institute for Chemisty, Rijksuniversiteit Groningen, The Netherlands.

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Supplementary Material

Supporting Information