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Synthesis 2020; 52(05): 673-687
DOI: 10.1055/s-0039-1690038
DOI: 10.1055/s-0039-1690038
short review
Ethenesulfonyl Fluoride (ESF) and Its Derivatives in SuFEx Click Chemistry and More
We are grateful to the National Natural Science Foundation of China (Grant No. 21772150), the Wuhan Applied Fundamental Research Plan of Wuhan Science and Technology Bureau (Grant No. 2017060201010216), the 111 Project (Grant No. B18038) and Wuhan University of Technology for the financial support.Further Information
Publication History
Received: 23 October 2019
Accepted after revision: 18 November 2019
Publication Date:
09 December 2019 (online)
Abstract
The sulfur(VI) fluoride exchange reaction (SuFEx), developed by Sharpless and co-workers in 2014, is a new category of click reaction that creates molecular connections with absolute reliability and unprecedented efficiency through a sulfur(VI) hub. Ethenesulfonyl fluoride (ESF), as one of the most important sulfur(VI) hubs, exhibits extraordinary reactivity in SuFEx click chemistry and organic synthesis. This review summarizes the chemical properties and applications of ESF in click chemistry, organic chemistry, materials science, medicinal chemistry and in many other fields related to organic synthesis.
1 Introduction
2 Chemical Transformations of ESF
3 Chemical Transformations of 2-Arylethenesulfonyl Fluorides
4 Novel SuFEx Reagents Derived from ESF
5 Applications of ESF Derivatives in Medicinal Chemistry
6 Applications of ESF Derivatives in Materials Science
7 Conclusion
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