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Synlett 2019; 30(18): 2051-2057
DOI: 10.1055/s-0039-1690154
DOI: 10.1055/s-0039-1690154
account
Functional End Groups in Living Ring-Opening Metathesis Polymerization
The author thanks the Swiss National Science Foundation and the Fribourg Centre for Nanomaterials (Frimat) for financial support.Weitere Informationen
Publikationsverlauf
Received: 27. Juni 2019
Accepted after revision: 24. Juli 2019
Publikationsdatum:
19. August 2019 (online)
Abstract
Over the last two decades many synthetic methods have been reported to selectively introduce a number of different functional groups at the chain end of a living ring-opening metathesis polymer. In this personal account, I would like to focus on a few such methods developed in my research group over the last several years and how these led to the discovery of catalytic living ring-opening metathesis polymerization, a ring-opening metathesis polymerization method controlled by the polymer end groups. This account consists of the following sections:
1 Introduction
2 Functionalization of the Propagating Chain End
3 Functionalization of the Initiating Chain End
4 Polymerization Control by Functional End Groups
5 Conclusions
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