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Synthesis 2020; 52(07): 1131-1139
DOI: 10.1055/s-0039-1691643
DOI: 10.1055/s-0039-1691643
paper
Synthesis of Chiral Tertiary Amine–Thioureas Based on Spirobiindane and Application in Catalytic Asymmetric Michael Addition Reaction
This work was funded by the National Natural Science Foundation of China (21572200).Further Information
Publication History
Received: 19 November 2019
Accepted after revision: 18 December 2019
Publication Date:
04 February 2020 (online)
Abstract
A series of novel chiral bifunctional tertiary amine–thioureas based on spirobiindane were designed and synthesized as organocatalysts. One of these catalysts was shown to promote the asymmetric Michael addition reaction of 1,3-diphenylpropane-1,3-dione to nitroolefins, affording the desired products in good yields (up to 95%) and enantioselectivities (up to 98% ee).
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1691643.
- Supporting Information
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