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DOI: 10.1055/s-0040-1706024
Photocatalytic Generation of π-Allyltitanium Complexes from Butadiene via a Radical Strategy
The project was supported by Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University (No.2020YB03), National College Student Innovation and Entrepreneurship Training Program Support Project, Dalian University of Technology (No. 2020101410101010339), and LiaoNing Revitalization Talents Program (No. XLYC1907126).
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Abstract
The direct conversion of industrial feedstock chemicals into highly valuable fine chemical intermediates is of great appeal to the synthetic community as well as industrial applications. This study reports a conceptually new radical strategy for the photocatalytic generation of π-allyltitanium complexes from butadiene. This novel and environmentally benign strategy enables the direct three-component allylation of carbonyls with 1,3-butadiene and α-bromocarboxylates, providing rapid access to valuable homoallylic alcohols with exceptional regio- and diastereoselectivity control.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1706024.
- Supporting Information
Publikationsverlauf
Eingereicht: 16. Dezember 2020
Angenommen nach Revision: 15. Januar 2021
Artikel online veröffentlicht:
18. Februar 2021
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