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DOI: 10.1055/s-0040-1706048
Visible-Light-Mediated Photocatalytic Oxidative C–C Bond Cleavage of Geminal Diazides: An Approach to Oxamates
We gratefully acknowledge the Council of Scientific and Industrial Research (02(0297)/17/EMR-II), Government of India and the Indian Institute of Technology Hyderabad (IITH) for financial support. N.R.K. thanks the Indian Institute of Technology Hyderabad (IITH) and the Science and Engineering Research Board, Department of Science and Technology, Ministriy of Science and Technology, India (DST-SERB), and A.V.M thanks the University Grants Committee (UGC) for the award of research rellowships.
Dedicated to all covid-19 warriors
Abstract
Photoredox catalysis has received great attention in both academia and industry and remarkable progress has been made over the past decade. Now, it has been shown that a visible-light-mediated oxidative C–C bond cleavage of geminal diazides can be induced by organic dye catalysis for the synthesis of oxamates. A mechanistic study, confirmed by control experiments, indicates that this proceeds through single-electron transfer (SET). This methodology can be applied to convert a wide array of geminal diazides into oxamates.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1706048.
- Supporting Information
Publication History
Received: 05 May 2021
Accepted after revision: 18 May 2021
Article published online:
17 June 2021
© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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