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Synlett 2021; 32(03): 258-266
DOI: 10.1055/s-0040-1707231
DOI: 10.1055/s-0040-1707231
account
Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
This research was funded by the Israel Science Foundation (Grant Number 506/18).Further Information
Publication History
Received: 25 June 2020
Accepted after revision: 04 July 2020
Publication Date:
07 August 2020 (online)
Abstract
This Account summarizes the historical development of latent sulfur-chelated ruthenium precatalysts from the Lemcoff group’s perspective. The most unique feature of this family of complexes is that they appear in the more stable cis-dichloro configuration, which is latent towards olefin metathesis reactions. Activation of the precatalyst, brought about by isomerization from the cis-dihalo to the trans-dihalo forms, can be achieved either by thermal or light stimuli. Modifications of the ligand sphere bestows unique properties upon the catalysts, which have been used in diverse applications, from 3D printing of metathesis polymers to orthogonally divergent synthetic pathways.
1 Introduction
2 Effect of Sulfur Substituents
3 Effect of Benzylidene Ligands
4 Effect of the NHC Ligands
5 Effect of the Anionic Ligands
6 Conclusions
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