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Synthesis 2020; 52(19): 2807-2820
DOI: 10.1055/s-0040-1707885
DOI: 10.1055/s-0040-1707885
short review
Nickel-Catalyzed anti-Selective Alkyne Functionalization Reactions
Further Information
Publication History
Received: 30 March 2020
Accepted after revision: 19 May 2020
Publication Date:
22 June 2020 (online)
Abstract
Nickel-catalyzed anti-selective alkyne functionalization reactions are reviewed with an emphasis on the mechanisms that lead to their observed stereoselectivity. Since the isomerization of alkenylnickel species plays a key role in a large number of these reactions, the potential mechanisms for these processes are also described in detail.
1 Introduction
2 anti-Selective Hydroarylation
3 anti-Selective Carboborylation
4 anti-Selective Dicarbofunctionalization
4.1 Carbocyanative Cyclization
4.2 Cyclization with Aryl Donors
4.3 Cyclization with CO2
4.4 Intermolecular Dicarbofunctionalization
5 anti-Selective Carbosulfonylation
6 Alkenylnickel Isomerization
7 Conclusions
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For reviews concerning alkyne hydroarylation, see: