SynOpen, Table of Contents CC BY-NC-ND 4.0 · SynOpen 2022; 06(01): 75-79DOI: 10.1055/s-0040-1719914 spotlight Tethered Rh(III)-N-(p-Tolylsulfonyl)-1,2-Diphenylethylene-1,2-Diamine Complexes: Efficient Catalysts for Asymmetric Transfer Hydrogenation Pierre-Georges Echeverria , Long-Sheng Zheng , Quentin Llopis , Bin He , Anne Westermeyer , Ricardo Molina Betancourt , Phannarath Phansavath∗ , Virginie Ratovelomanana-Vidal ∗ Recommend Article Abstract All articles of this category Abstract Key words Key wordsasymmetric catalysis - enantioselectivity - homogeneous catalysis - hydrogen transfer - rhodium - diastereoselectivity Full Text References References For comprehensive reviews and chapters on asymmetric transfer hydrogenation (ATH), see: 1a Zassinovich G, Mestroni G, Gladiali S. Chem. Rev. 1992; 92: 1051 1b de Graauw CF, Peters JA, van Bekkum H, Huskens J. Synthesis 1994; 1007 1c Noyori R, Hashiguchi S. Acc. Chem. Res. 1997; 30: 97 1d Palmer MJ, Wills M. Tetrahedron: Asymmetry 1999; 10: 2045 1e Pàmies O, Bäckvall J.-E. Chem. Eur. J. 2001; 7: 5052 1f Everaere K, Mortreux A, Carpentier J.-F. Adv. Synth. Catal. 2003; 345: 67 1g Gladiali S, Alberico E. Chem. Soc. Rev. 2006; 35: 226 1h Samec JS. M, Bäckvall J.-E, Andersson PG, Brandt P. Chem. Soc. Rev. 2006; 35: 237 1i Ikariya T, Blacker AJ. Acc. Chem. Res. 2007; 40: 1300 1j Blacker AJ. In Handbook of Homogeneous Hydrogenation . de Vries JG, Elsevier CJ. Wiley-VCH; Weinheim: 2007: 1215 1k Wang C, Wu X, Xiao J. Chem. Asian J. 2008; 3: 1750 1l Ikariya T. Bull. Chem. Soc. Jpn. 2011; 84: 1 1m Zheng C, You S.-L. Chem. Soc. Rev. 2012; 41: 2498 1n Bartoszewicz A, Ahlsten N, Martín-Matute B. Chem. Eur. J. 2013; 19: 7274 1o Slagbrand T, Lundberg H, Adolfsson H. Chem. Eur. J. 2014; 20: 16102 1p Wang D, Astruc D. Chem. Rev. 2015; 115: 6621 1q Foubelo F, Nájera C, Yus M. Tetrahedron: Asymmetry 2015; 26: 769 1r Li Y.-Y, Yu S.-L, Shen W.-Y, Gao J.-X. Acc. Chem. Res. 2015; 48: 2587 1s Nedden HG, Zanotti-Gerosa A, Wills M. Chem. Rec. 2016; 16: 2623 1t Ayad T, Phansavath P, Ratovelomanana-Vidal V. Chem. Rec. 2016; 16: 2754 1u Milner L, Talavera G, Nedden HG. Chim. Oggi 2017; 35: 37 1v Matsunami A, Kayaki Y. Tetrahedron Lett. 2018; 59: 504 1w Talavera G, Santana Fariña A, Zanotti-Gerosa A, Nedden HG. In Topics in Organometallic Chemistry, Vol 65. Colacot TJ, Sivakumar V. Springer; Berlin, Heidelberg: 2019: 73 1x Asymmetric Hydrogenation and Transfer Hydrogenation . Ratovelomanana-Vidal V, Phansavath P. Wiley-VCH; Weinheim: 2021 1y Cotman AE. Chem. Eur. J. 2021; 27: 39 2a Hashiguchi S, Fujii A, Takehara J, Ikariya T, Noyori R. J. Am. Chem. Soc. 1995; 117: 7562 2b Haack K.-J, Hashiguchi S, Fujii A, Ikariya T, Noyori R. Angew. Chem., Int. Ed. Engl. 1997; 36: 285 3 Matharu DS, Morris DJ, Kawamoto AM, Clarkson GJ, Wills M. Org. Lett. 2005; 7: 5489 4a Echeverria P.-G, Férard C, Phansavath P, Ratovelomanana-Vidal V. Catal. Commun. 2015; 62: 95 4b Zheng L.-S, Llopis Q, Echeverria P.-G, Férard C, Guillamot G, Phansavath P, Ratovelomanana-Vidal V. J. Org. Chem. 2017; 82: 5607 5 He B, Zheng L.-S, Phansavath P, Ratovelomanana-Vidal V. ChemSusChem 2019; 12: 3032 6 Matharu DS, Martins JE. D, Wills M. Chem. Asian J. 2008; 3: 1374 7 Llopis Q, Férard C, Guillamot G, Phansavath P, Ratovelomanana-Vidal V. Synthesis 2016; 48: 3357 For selected reviews on DKR, see: 8a Noyori R, Tokunaga M, Kitamura M. Bull. Chem. Soc. Jpn. 1995; 68: 36 8b Pellissier H. Tetrahedron 2011; 67: 3769 8c Molina Betancourt R, Echeverria P.-G, Ayad T, Phansavath P, Ratovelomanana-Vidal V. Synthesis 2021; 53: 30 9 Zheng L.-S, Férard C, Phansavath P, Ratovelomanana-Vidal V. Chem. Commun. 2018; 54: 283 10 He B, Phansavath P, Ratovelomanana-Vidal V. Org. Lett. 2019; 21: 3276 11 Westermeyer A, Guillamot G, Phansavath P, Ratovelomanana-Vidal V. Org. Lett. 2020; 22: 3911 12 He B, Phansavath P, Ratovelomanana-Vidal V. Org. Chem. Front. 2020; 7: 975 13 Molina Betancourt R, Phansavath P, Ratovelomanana-Vidal V. Org. Lett. 2021; 23: 1621 14 He B, Phansavath P, Ratovelomanana-Vidal V. Org. Chem. Front. 2021; 8: 2504 15 Wang F, Zheng L.-S, Lang Q.-W, Yin C, Wu T, Phansavath P, Chen G.-Q, Ratovelomanana-Vidal V, Zhang X. Chem. Commun. 2020; 56: 3119 16 Wang F, Yang T, Wu T, Zheng L.-S, Yin C, Shi Y, Ye X.-Y, Chen G.-Q, Zhang X. J. Am. Chem. Soc. 2021; 143: 2477
