Transborylation-Enabled Boron Catalysis

Andrew D. Bage; Kieran Nicholson; Thomas A. Hunt; Thomas Langer; Stephen P. Thomas

doi:10.1055/s-0040-1720046

Synthesis, Inhaltsverzeichnis

Synthesis 2023; 55(01): 62-74
DOI: 10.1055/s-0040-1720046

short review

Transborylation-Enabled Boron Catalysis

Andrew D. Bage

^aEaStCHEM School of Chemistry, The University of Edinburgh, Edinburgh EH9 3FJ, UK

,

Kieran Nicholson

^aEaStCHEM School of Chemistry, The University of Edinburgh, Edinburgh EH9 3FJ, UK

,

Thomas A. Hunt

^bMedicinal Chemistry, Early Oncology, AstraZeneca, Cambridge CB4 0WG, UK

,

Thomas Langer

^cPharmaceutical Technology & Development, Chemical Development U.K., AstraZeneca, Macclesfield SK10 2NA, UK

,

Stephen P. Thomas ∗

^aEaStCHEM School of Chemistry, The University of Edinburgh, Edinburgh EH9 3FJ, UK

› Institutsangaben

Abstract

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Abstract

This review highlights transborylation (controlled boron-boron exchange) and its applications as a turnover strategy in boron-catalysed methodologies. Catalytic applications of B–C, B–O, B–N, B–F, B–S, and B–Se transborylations are discussed in the context of transborylation-enabled catalysis, across a wide range of organic transformations including hydroboration, C–C bond formation, C–H borylation, chemoselective reduction, and asymmetric reduction.

1 Introduction

2 B–C Transborylation

3 B–O Transborylation

4 B–N Transborylation

5 B–F Transborylation

6 B–S Transborylation

7 Conclusion

Key words

transborylation - boron - main group - catalysis - metathesis

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Referenzen

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