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CC BY-NC-ND 4.0 · Organic Materials 2021; 03(02): 146-154
DOI: 10.1055/s-0041-1727182
Focus Issue: Peter Bäuerle 65th Birthday
Short Review

Supramolecular Approaches for Taming the Chemo- and Regiochemistry of C60 Addition Reactions

Sebastian B. Beil 
a   Institute of Organic Chemistry, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany
b   Current address: Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States
,
Max von Delius 
a   Institute of Organic Chemistry, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany
› Institutsangaben Funding Information We are grateful for financial support from the Deutsche Forschungsgemeinschaft (DFG, 182849149-SFB953, 364549901–TRR 234, DE1830/1, DE1830/5), the European Research Council (ERCstg 802428 SUPRANET) and the University of Ulm.
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Abstract

The chemo- and regioselective functionalization of fullerenes is a long-standing problem of organic synthesis. Over the past five years, this fundamental challenge has gained technological relevance, because studies on single bis-adduct isomers in new-generation solar cells have demonstrated that the widespread use of isomer mixtures leads to suboptimal power conversion efficiencies. Herein, we review recent work on supramolecular approaches for achieving chemo- and regioselective syntheses of multiply functionalized derivatives of C60.

Key words

fullerenes - template effect - supramolecular chemistry - regioselectivity - organic photovoltaics - host–guest chemistry

Dedicated to Prof. Peter Bäuerle on the occasion of his 65th birthday.




Publikationsverlauf

Eingereicht: 15. Januar 2021

Angenommen: 09. Februar 2021

Artikel online veröffentlicht:
01. April 2021

© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 

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