Nickel-Catalyzed Electrochemical Cyclizative Carboxylation of Alkene-Tethered Carbamoyl Chlorides with Carbon Dioxide

Abstract

Nickel-catalyzed electrochemical cyclizative carboxylation of alkene-tethered carbamoyl chlorides with atmospheric carbon dioxide in an undivided cell under simple constant current conditions is reported. This reaction is conducted with high efficiency under mild conditions, providing a convenient and green access to valuable 2-oxoindolin-3-ylacetic acids and 2-oxo-tetrahydroquinoline-4-carboxylic acids.

Key words

carbon dioxide - cyclizative carboxylation - organic electrosynthesis - nickel catalysis - carbamoyl chlorides

Publication History

Received: 17 February 2023

Accepted after revision: 13 April 2023

Article published online:
16 May 2023

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