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Synthesis 2023; 55(13): 2011-2018
DOI: 10.1055/s-0042-1751433
DOI: 10.1055/s-0042-1751433
paper
Visible-Light-Driven Iodine-Catalyzed Synthesis of Unsymmetrical Disulfides via Oxidative Coupling
We are thankful for the financial support from the National Natural Science Foundation of China (nos. 22067018, 22061038) and the Key Talent Projects of Gansu Province (2019-39).
Abstract
Herein, a facile and environmentally friendly oxidative coupling reaction to obtain unsymmetrical disulfide compounds, without using metal or organic dyes as photocatalyst and only using a catalytic amount of iodine, was developed. Oxygen is used as oxidant in the reaction and the substrate scope is wide. A gram-scale synthesis also highlights the synthetic practicality of this photochemical strategy. Moreover, our mechanistic studies support the formation of disulfide products through free-radical coupling.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0042-1751433.
- Supporting Information
Publication History
Received: 29 December 2022
Accepted after revision: 22 February 2023
Article published online:
27 March 2023
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