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DOI: 10.1055/s-0042-1751520
Dearomatization of α-Unsubstituted β-Naphthols
We are grateful for financial support from the National Natural Science Foundation of China (21801087), the Fundamental Research Funds for the Central Universities, and the Central China Normal University (CCNU19QN064).
Abstract
This Account summarizes the highly appealing dearomatization reactions of β-naphthols for the synthesis of highly functionalized, three-dimensional structures starting with simple planar aromatic compounds. The reactions are categorized mainly from the viewpoint of the construction of carbon–hydrogen, carbon–carbon, and carbon–hetero bonds (C–N/O, C–Cl, C–F) at the α-position of β-naphthols. The dearomatized products play an important role in organic synthesis and materials science.
1 Introduction
2 Construction of Carbon–Hydrogen Bonds at the α-Position of β-Naphthols
3 Construction of Carbon–Carbon Bonds at the α-Position of β-Naphthols
4 Construction of Carbon–Nitrogen/Oxygen Double Bond at the α-Position of β-Naphthols
5 Construction of Carbon–Carbon and Carbon–Oxygen Bonds at the α-Position of β-Naphthols
6 Construction of Carbon–Halogen Bonds at the α-Position of β-Naphthols
7 Conclusion
Publication History
Received: 15 September 2023
Accepted after revision: 05 October 2023
Article published online:
10 November 2023
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