CC BY 4.0 · Organic Materials 2024; 06(02): 66-70
DOI: 10.1055/s-0044-1787016
Covalent Organic Frameworks (COFs)
Short Communication

Metal-Catalyzed Multi-Component Approach to Quinoline-Linked Covalent Organic Frameworks

a   Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, Advanced Technology Research Institute (Jinan), Frontiers Science Center for High Energy Material, School of Chemistry and Chemical Engineering, Beijing Institute of Technology. No. 5, South Street, Zhongguancun, Haidian District, Beijing 100081, P. R. of China
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a   Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, Advanced Technology Research Institute (Jinan), Frontiers Science Center for High Energy Material, School of Chemistry and Chemical Engineering, Beijing Institute of Technology. No. 5, South Street, Zhongguancun, Haidian District, Beijing 100081, P. R. of China
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a   Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, Advanced Technology Research Institute (Jinan), Frontiers Science Center for High Energy Material, School of Chemistry and Chemical Engineering, Beijing Institute of Technology. No. 5, South Street, Zhongguancun, Haidian District, Beijing 100081, P. R. of China
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Abstract

The development of new reaction chemistry is highly desirable to construct new structural and functional covalent organic frameworks (COFs). Benefiting from the extremely large database of metal-catalyzed reaction database, we herein develop a new synthetic strategy that can generate quinoline-linked COFs via a silver-catalyzed three-component one-pot reaction and achieve functionalization by the simple replacement of alcohols. This metal-catalyzed approach to the construction of robust COF structures characterized by extended π-conjugation holds the potential to pave a novel pathway in the synthesis of COF materials endowed with both heightened stability and functionality.



Publikationsverlauf

Eingereicht: 01. Februar 2024

Angenommen nach Revision: 18. April 2024

Artikel online veröffentlicht:
17. Mai 2024

© 2024. The Authors. This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/).

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