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Synthesis 1986; 1986(3): 222-224
DOI: 10.1055/s-1986-31624
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Herstellung von Vinyl-iodiden durch Umsetzung von Vinyl-triflaten mit Magnesiumiodid

A. García Martínez* , R. Martínez Alvarez, A. García Fraile, L. R. Subramanian, Michael Hanack
  • *Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, Ciudad Universitaria, E-28040 Madrid, Spain
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Publication Date:
20 August 2002 (online)

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Synthesis of Vinyl Iodides from Vinyl Triflates and Magnesium Iodide The reaction of vinyl trifluoromethanesulfonates (triflates) with anhydrous magnesium iodide in the presence of triethylamine in carbon disulfide or cyclohexane gives vinyl iodides in good yields. No reaction is observed with phenyl and cyclopentenyl triflate under these conditions.