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Synthesis 1987; 1987(11): 1037-1039
DOI: 10.1055/s-1987-28165
DOI: 10.1055/s-1987-28165
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A New and Easy Synthesis of Diethyl 2-Formylalkylphosphonates
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Publikationsverlauf
Publikationsdatum:
12. September 2002 (online)
Aldimines obtained from 2-alkenals are condensed with triethyl phosphite in ethanol in the presence of formic acid to give diethyl iminoalkylphosphonates; these are readily converted into diethyl formylalkylphosphonates in acidic medium.