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Synthesis 1987; 1987(12): 1093-1096
DOI: 10.1055/s-1987-28179
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Hydro-dehalogenation of α-Haloketones by Halogen and Pseudo Halogen, Sulfur and Aromatic Compounds in Combination with Metal Halides

Aoi Ono* , Tamiko Maruyama, Junko Kamimura
  • *Department of Chemistry, Faculty of Education, Niigata University Niigata, 950-21 Japan
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Publication Date:
20 August 2002 (online)

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α-Haloketones 1 were successfully hydro-dehalogenated to their corresponding ketones 2 by sulfur and aromatic compounds (benzene, aniline and pyridine) in combination with metal halides in tetrahydrofuran. For comparison, α-haloketones 1 were also dehalogenated by metal halides alone in tetrahydrofuran.