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Synthesis 1988; 1988(1): 58-60
DOI: 10.1055/s-1988-27464
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Regiospezifische Herstellung von primären Allylacetaten (2-Alkenyl-acetaten)

Antonio García Martínez* , Angeles Cruces Villalobos, Manuel Oliver Ruiz
  • *Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, E-28040 Madrid, Spain
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Publication Date:
12 September 2002 (online)

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Regiospecific Preparation of Primary Allyl Acetates (2-Alkenyl Acetates) The reaction of primary, secondary and tertiary allyl alcohols 1 with anhydrous magnesium iodide in benzene gives regiospecifically the primary allyl iodides 2. The corresponding primary allyl acetates 3 are obtained regiospecifically by reaction of 2 with anhydrous sodium acetate in dimethylformamide.