2,4-Dioxaadamantane

Andrew J. Briggs; Anthony J. Kirby

doi:10.1055/s-1988-27467

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Synthesis 1988; 1988(1): 66-67
DOI: 10.1055/s-1988-27467

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2,4-Dioxaadamantane

Andrew J. Briggs^* , Anthony J. Kirby

^*University Chemical Laboratory, Cambridge, CB2 1EW, England, GB

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Publication History

Publication Date:
12 September 2002 (online)

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2,4-Dioxatricyclo[3.3.1.1^3,7]decane, a unique acetal with both oxygens axial on tetrahydropyran rings, is formed spontaneously when all-cis 3,5-dihydroxy-1-cyclohexaneacetaldehyde is generated in acid.