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Synthesis 1988; 1988(5): 404-406
DOI: 10.1055/s-1988-27595
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A Novel Synthesis of Thiocarboxylic S-Esters from 1-(Acylthio)ethaniminium Halides and Alkyl Halides Using Liquid-Liquid Phase-Transfer Catalysis

Toshio Takido* , Masaharu Toriyama, Kunio Itabashi
  • *Department of Industrial Chemistry, College of Science and Technology, Nihon University, Kanda Surugadai, Chiyoda-ku, Tokyo 101, Japan
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Publication Date:
20 August 2002 (online)

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S-Alkyl, S-benzyl, and S-(2-alkenyl) thiocarboxylates are prepared in good yields by acylation of thioacetamide with aryl halides and reaction of the resultant 1-(acylthio)ethaniminium halides with alkyl halides under liquid-liquid phase-transfer conditions.