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Synthesis 1989; 1989(1): 8-12
DOI: 10.1055/s-1989-27130
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Preparation of ω-Chloroimines

Paul Sulmon* , Norbert De Kimpe, Niceas Schamp
  • *Laboratory of Organic Chemistry, Faculty of Agricultural Sciences, State University of Gent, Coupure Links 653, B-9000 Gent, Belgium
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Publication History

Publication Date:
27 September 2002 (online)

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Alkylation of 1-azaallylic anions (generated by deprotonation of alkanimines) with 1,ω-dihaloalkanes provides a useful procedure for the synthesis of δ-chloro- and ε-chloroalkanimines. These ω-haloalkanimines have not been isolated and characterized before, although some representatives were already used as intermediates in some transformations.