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Synthesis 1989; 1989(8): 614-616
DOI: 10.1055/s-1989-27334
DOI: 10.1055/s-1989-27334
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A Simple Method for the Conversion of Adamantyl, Benzyl and Benzyhydryl Alcohols to Their Corresponding Bromides and Chlorides and the Transhalogenation of Adamantyl, Benzyl, Benzhydryl and Tertiary Alkyl Bromides and Chlorides
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Publication History
Publication Date:
17 September 2002 (online)
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Adamantyl, benzyl, and benzhydryl alcohols have been converted to their corresponding bromides and chlorides in the absence of a solvent, rapidly and in high yield using boron tribromide and tin(IV) chloride, respectively. Additionally the above bromides and chlorides can be interconverted by a transhalogenation process using the same reagents in the absence of solvent.