Download PDF
Synthesis 1989; 1989(12): 929-932
DOI: 10.1055/s-1989-27432
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Organotin Selenocarboxylates: Synthesis and Some Reactions

Hideharu Ishihara* , Shinya Muto, Toyohiko Endo, Mutsuaki Komada, Shinzi Kato
  • *Department of Chemistry, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu 501-11, Japan
Further Information

Publication History

Publication Date:
02 May 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

A series of di- 3 and triorganotin esters 2 of aromatic selenocarboxylic acid were synthesized and characterized. The organotin esters 2 and 3 are stable thermally, but labile towards moisture and oxygen. They readily reacted with benzyl bromide in the presence of aluminum chloride to afford benzyl selenocarboxylates 4 in moderate yields. The reaction of triphenyltin selenocarboxylates with phenylselenenyl bromide led to aryl phenyl diselenides 5 in good yields.