Download PDF
Synlett 1990; 1990(4): 205-206
DOI: 10.1055/s-1990-21034
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Iodonium Ion Promoted Reactions at the Anomeric C-2 Center of 1-Methylene Sugars

Daan Noort* , Gerrit H. Veeneman, Geert-Jan P. H. Boons, Gijs A. van der Marel, Gerard J. Mulder, Jacques H. van Boom
  • *Gorlaeus Laboratoria, Rijksuniversiteit Leiden, P.O. Box 9502, NL-2300 RA Leiden, The Netherlands
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.