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Synlett 1990; 1990(7): 411-413
DOI: 10.1055/s-1990-21109
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Reaction of Allylstannanes with Cationic α,β-Unsaturated Alkoxycarbene-Iron Complexes

James W. Herndon* , Chao Wu
  • *Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA
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Publication Date:
08 March 2002 (online)

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Reaction of allylstannanes with cationic α,β-unsaturated alkoxycarbene-iron complexes leads to 5-hexenoyliron complexes. Subsequent treatment with N-bromosuccinimide and alcohols leads to the corresponding esters.