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Synthesis 1990; 1990(1): 53-56
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Efficient Preparation of Optically Pure Wieland-Miescher Ketone and Confirmation of Its Absolute Stereochemistry by the CD Exciton Chirality Method

Nobuyuki Harada* , Tatsuo Sugioka, Hisashi Uda, Takeo Kuriki
  • *Chemical Research Institute of Nonaqueous Solutions, Tohoku University, 2-1-1 Katahira, Sendai 980, Japan
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Publikationsdatum:
17. September 2002 (online)

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An efficient preparation procedure of optically pure Wieland-Miescher ketone, (8aR)-(-)-3,4,8,8a-tetrahydro-8a-methyl-1,6(2H, 7H)-naphthalenedione (1), is described, and its absolute stereochemistry is confirmed by the application of the CD exciton chirality method to its derivatives.